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Issue 5, 2009
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Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

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Abstract

The well-defined conformation of an N,N′-diarylurea allows a chiral sulfinyl substituent to influence diastereoselectivity in the formation of new stereogenic centres up to 14 bond lengths away.

Graphical abstract: Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

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Article information


Submitted
06 Oct 2008
Accepted
10 Nov 2008
First published
26 Nov 2008

Chem. Commun., 2009, 547-549
Article type
Communication

Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

J. Clayden, M. Pickworth and L. H. Jones, Chem. Commun., 2009, 547
DOI: 10.1039/B817527F

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