Issue 6, 2008
From the journal:

Photochemical & Photobiological Sciences

Novel perfluorodiphenylphosphinic acid lanthanide (Er or Er–Yb) complex with high NIR photoluminescence quantum yield†

Limei Song,ab   Jin Hu,ab   Jianshe Wang,ab   Xinhou Liua  and  Zhen Zhen*a  

* Corresponding authors

a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, P. R. China
E-mail: zhenz@mail.ipc.ac.cn
Fax: 86 010 62554670

b The Graduate University of Chinese Academy of Sciences, Beijing, P. R. China

Abstract

A perfluorodiphenylphosphinic acid lanthanide (Er or Er–Yb) complex is synthesized by a one-pot process from perfluorotriphenylphosphine oxide and lanthanide (Er or Er–Yb) chloride; the photoluminescence quantum efficiency reaches 0.98% for the erbium complex and 3.5% for the erbium–ytterbium complex, about 50 times and 175 times, respectively, higher than the usual erbium organic complexes with the hydrogen-containing ligands.

Graphical abstract: Novel perfluorodiphenylphosphinic acid lanthanide (Er or Er–Yb) complex with high NIR photoluminescence quantum yield

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Article information

DOI
https://doi.org/10.1039/B804117B
Article type
Paper
Submitted
10 Mar 2008
Accepted
06 May 2008
First published
13 May 2008

Photochem. Photobiol. Sci., 2008,7, 689-693

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Novel perfluorodiphenylphosphinic acid lanthanide (Er or Er–Yb) complex with high NIR photoluminescence quantum yield

L. Song, J. Hu, J. Wang, X. Liu and Z. Zhen, Photochem. Photobiol. Sci., 2008, 7, 689 DOI: 10.1039/B804117B

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