Issue 21, 2008
From the journal:

Organic & Biomolecular Chemistry

An unexpected epoxidation of benzil derivatives in their reaction with a germene†

Sakina Ech-Cherif El Kettani,a   Mohamed Lazraq,a   Fatima Ouhsaine,ab   Heinz Gornitzka,b   Henri Ranaivonjatovob  and  Jean Escudié*b  

* Corresponding authors

a Laboratoire d'Ingénierie Moléculaire et Organométallique (LIMOM), BP 1796, Faculté des Sciences Dhar El Mehraz, Université Sidi Mohamed Ben Abdellah, Fès-Atlas, Fès, Morocco
Fax: +212 55642500
Tel: +212 55642382

b Laboratoire Hétérochimie Fondamentale et Appliquée, UMR-CNRS 5069, Université Paul Sabatier, 118 route de Narbonne, France
E-mail: escudie@chimie.ups-tlse.fr
Fax: +33 561558204
Tel: +33 561558347

Abstract

The germene Mes2Ge[double bond, length as m-dash]CR2 (Mes = 2,4,6-trimethylphenyl, CR2 = fluorenylidene) reacts with various benzil derivatives to lead to germanium-containing bicyclic epoxides by an unexpected new type of epoxidation reaction.

Graphical abstract: An unexpected epoxidation of benzil derivatives in their reaction with a germene

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Article information

DOI
https://doi.org/10.1039/B812694C
Article type
Paper
Submitted
23 Jul 2008
Accepted
01 Aug 2008
First published
10 Sep 2008

Org. Biomol. Chem., 2008,6, 4064-4066

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An unexpected epoxidation of benzil derivatives in their reaction with a germene

S. E. El Kettani, M. Lazraq, F. Ouhsaine, H. Gornitzka, H. Ranaivonjatovo and J. Escudié, Org. Biomol. Chem., 2008, 6, 4064 DOI: 10.1039/B812694C

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