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Friedel–Crafts allylic alkylation of a wide variety of aromatic and heteroaromatic compounds with allylic alcohols catalysed by AuCl3 (5 mol%) under mild conditions at room temperature was accomplished in good to excellent yields (up to 99%) and regioselectivity.

Graphical abstract: Gold-catalysed allylic alkylation of aromatic and heteroaromatic compounds with allylic alcohols

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