Issue 15, 2008
From the journal:

Organic & Biomolecular Chemistry

Reagent switchable stereoselective β(1,2) mannoside mannosylation: OH-2 of mannose is a privileged acceptor†‡

Katie J. Dooresa  and  Benjamin G. Davis*a  

* Corresponding authors

a Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, UK
E-mail: ben.davis@chem.ox.ac.uk
Fax: +44 (0) 1865 275674
Tel: +44 (0) 1865 275654

Abstract

The discovery of novel conditions for highly β-stereoselective (>9 : 1) mannosylation of OH-2 of mannosides using a straightforward perbenzylthioglycoside donor has allowed ready assembly of β-mannosyl oligosaccharides including the repeating trisaccharide motif of the O5 antigen of pathogen Klebsiella pneumoniae.

Graphical abstract: Reagent switchable stereoselective β(1,2) mannoside mannosylation: OH-2 of mannose is a privileged acceptor

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Article information

DOI
https://doi.org/10.1039/B803999M
Article type
Paper
Submitted
07 Mar 2008
Accepted
22 Apr 2008
First published
02 Jun 2008

Org. Biomol. Chem., 2008,6, 2692-2696

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Reagent switchable stereoselective β(1,2) mannoside mannosylation: OH-2 of mannose is a privileged acceptor

K. J. Doores and B. G. Davis, Org. Biomol. Chem., 2008, 6, 2692 DOI: 10.1039/B803999M

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