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A mild and efficient one pot method for the synthesis of indolo[3,2-a]carbazole derivatives by the para-toluenesulfonic acid catalyzed condensation of indole with acyclic 1,2-diones is described. With cyclobutene-1,2-diones the reaction afforded indole substituted carbazole derivatives in good yield.

Graphical abstract: An efficient synthesis of indolo[3,2-a]carbazoles via the novel acid catalyzed reaction of indoles and diaryl-1,2-diones

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