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Issue 8, 2008
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Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane

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Abstract

A series of propargylic tertiary alcohols decorated with an sp2-hybridised nitrogen donor were kinetically resolved by reagent-controlled dehydrogenative Si–O coupling with a strained, highly reactive silicon-stereogenic cyclic silane.

Graphical abstract: Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane

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Article information


Submitted
07 Feb 2008
Accepted
11 Feb 2008
First published
29 Feb 2008

Org. Biomol. Chem., 2008,6, 1435-1440
Article type
Paper

Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane

B. Karatas, S. Rendler, R. Fröhlich and M. Oestreich, Org. Biomol. Chem., 2008, 6, 1435
DOI: 10.1039/B802186D

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