Issue 8, 2008
From the journal:

Organic & Biomolecular Chemistry

Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane†

Betül Karatas,a   Sebastian Rendler,a   Roland Fröhlich‡a  and  Martin Oestreich*a  

* Corresponding authors

a Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstrasse 40, Münster, Germany
E-mail: martin.oestreich@uni-muenster.de
Fax: +49 (0)251 83-36501
Tel: +49 (0)251 83-33271

Abstract

A series of propargylic tertiary alcohols decorated with an sp2-hybridised nitrogen donor were kinetically resolved by reagent-controlled dehydrogenative Si–O coupling with a strained, highly reactive silicon-stereogenic cyclic silane.

Graphical abstract: Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane

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Article information

DOI
https://doi.org/10.1039/B802186D
Article type
Paper
Submitted
07 Feb 2008
Accepted
11 Feb 2008
First published
29 Feb 2008

Org. Biomol. Chem., 2008,6, 1435-1440

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Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane

B. Karatas, S. Rendler, R. Fröhlich and M. Oestreich, Org. Biomol. Chem., 2008, 6, 1435 DOI: 10.1039/B802186D

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