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Abstract | Cited by

The rates of radical generation, Ri, by two water soluble initiators: 2,2′-azobis(2-methylpropionamidine) and 2,2′-azobis[2-methyl-N-(2-hydroxyethyl)propionamide], and the lipid soluble 2,2′-azobisisobutyronitrile were measured in an SDS micellar system over a pH range of 4–10. Enhanced values of Ri at low pH are attributed to Coulombic repulsion of protonated radicals.

Graphical abstract: Initiation of lipid autoxidation by ABAP at pH 4–10 in SDS micelles

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