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Issue 5, 2008
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Organometallic compounds containing new Hf–Ga and Hf–In bonds: Cp2Hf(ER)2 (Cp = C5H5; E = Ga, In; R = –C6H3-2,6-(2,4,6-i-Pr3C6H2)2)

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Abstract

Sodium metal reduction of RECl2 (E = Ga, In; R = –C6H3-2,6-(2,4,6-i-Pr3C6H2)2) with Cp2HfCl2 gives Cp2Hf(ER)2 compounds, which represent the first Hf–E bonds.

Graphical abstract: Organometallic compounds containing new Hf–Ga and Hf–In bonds: Cp2Hf(ER)2 (Cp = C5H5; E = Ga, In; R = –C6H3-2,6-(2,4,6-i-Pr3C6H2)2)

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Article information


Submitted
30 Nov 2007
Accepted
08 Feb 2008
First published
19 Feb 2008

New J. Chem., 2008,32, 774-776
Article type
Letter

Organometallic compounds containing new Hf–Ga and Hf–In bonds: Cp2Hf(ER)2 (Cp = C5H5; E = Ga, In; R = –C6H3-2,6-(2,4,6-i-Pr3C6H2)2)

B. Quillian, Y. Wang, P. Wei and G. H. Robinson, New J. Chem., 2008, 32, 774
DOI: 10.1039/B718429H

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