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Abstract | Cited by

Sodium metal reduction of RECl2 (E = Ga, In; R = –C6H3-2,6-(2,4,6-i-Pr3C6H2)2) with Cp2HfCl2 gives Cp2Hf(ER)2 compounds, which represent the first Hf–E bonds.

Graphical abstract: Organometallic compounds containing new Hf–Ga and Hf–In bonds: Cp2Hf(ER)2 (Cp = C5H5; E = Ga, In; R = –C6H3-2,6-(2,4,6-i-Pr3C6H2)2)

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