Several new supramolecular s-tetrazines have been prepared and studied. Their electrochemical and spectroscopic properties have been investigated, especially in the presence of quenchers. Fluorescence quenching has been shown to occur as expected through a charge transfer mechanism and the cyclophane structure has been shown to lead to an acceleration of the quenching process.
Y. Gong, P. Audebert, G. Clavier, F. Miomandre, J. Tang, S. Badré, R. Méallet-Renault and E. Naidus, New J. Chem., 2008, 32, 1235 DOI: 10.1039/B717998G
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