Issue 46, 2008
From the journal:

Dalton Transactions

Involvement of thiolate ligands in binding substrates to Fe–S clusters†

Katie Bates,a   Matthew Wouldhavea  and  Richard A. Henderson*a  

* Corresponding authors

a School of Chemistry, Newcastle University, Newcastle upon Tyne, UK
E-mail: r.a.henderson@ncl.ac.uk
Fax: +44 (0)191 222 6929
Tel: +44 (0)191 222 6636

Abstract

Kinetic studies on reactions between [Fe4S4(SR)4]2− (R = Et or But) and 4-YC6H4COCl (Y = MeO, H or Cl) to form [Fe4S4Cl4]2− and 4-YC6H4COSR indicate that the terminal thiolate ligand is involved in the initial binding of the acid chloride to the cluster.

Graphical abstract: Involvement of thiolate ligands in binding substrates to Fe–S clusters

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Article information

DOI
https://doi.org/10.1039/B817353M
Article type
Communication
Submitted
02 Oct 2008
Accepted
08 Oct 2008
First published
21 Oct 2008

Dalton Trans., 2008, 6527-6529

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Involvement of thiolate ligands in binding substrates to Fe–S clusters

K. Bates, M. Wouldhave and R. A. Henderson, Dalton Trans., 2008, 6527 DOI: 10.1039/B817353M

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