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Issue 27, 2008
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Synthesis of η1-borazine complexes of palladium and platinum

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Abstract

The η1-borazine complexes trans-[(Cy3P)2M(Br)(Br2B3N3H3)] (Cy = cyclohexyl) were prepared by oxidative additon of a B–Br bond of (BrBNH)3 to [M(PCy3)2] (M = Pd, Pt). Furthermore the platinum compound was converted into the T-shaped cationic complex trans-[(Cy3P)2Pt(Br2B3N3H3)][BArf4] [Arf = 3,5-(CF3)2C6H3] by addition of Na[BArf4].

Graphical abstract: Synthesis of η1-borazine complexes of palladium and platinum

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Publication details

The article was received on 28 Mar 2008, accepted on 02 May 2008 and first published on 21 May 2008


Article type: Communication
DOI: 10.1039/B805298K
Citation: Dalton Trans., 2008,0, 3531-3534
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    Synthesis of η1-borazine complexes of palladium and platinum

    H. Braunschweig, H. Green, K. Radacki and K. Uttinger, Dalton Trans., 2008, 0, 3531
    DOI: 10.1039/B805298K

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