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(TtztBu,Me)CuCO [TtztBu,Me = tris(3-t-butyl-5-methyl-1,2,4-triazolyl)borate] was prepared and fully characterized to test whether the TtztBu,Me ligand, which is sterically similar to TptBu,Me is electronically different; TtztBu,Me is a weaker electron donor and (TtztBu,Me)CuCO is water stable and has a propensity to form hydrogen bonds.

Graphical abstract: How are tris(triazolyl)borate ligands electronically different from tris(pyrazolyl)borate ligands? A study of (TtztBu,Me)CuCO [TtztBu,Me = tris(3-t-butyl-5-methyl-1,2,4-triazolyl)borate]

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