Issue 30, 2008
From the journal:

Dalton Transactions

Multi-centre, hydrogen and dihydrogen bonds in lithium closo-hydroborate obtained from liquid ammonia†‡

Monalisa Panda,a   Kathrin Hofmann,a   Marc H. Prosencb  and  Barbara Albert*a  

* Corresponding authors

a Technische Universität Darmstadt, Petersenstrasse 18, Darmstadt, Germany
E-mail: albert@ac.chemie.tu-darmstadt.de
Fax: +49 (0)6151 166020
Tel: +49 (0)6151 162392

b University of Hamburg, Martin-Luther-King-Platz 6, Hamburg, Germany
E-mail: prosenc@chemie.uni-hamburg.de
Fax: +49 (0)40 42838 6945
Tel: +49 (0)40 42838 3102

Abstract

Charge density analysis reveals multi-centre bonds in the cluster, hydrogen bridges in the ammonia network, and the dihydrogen bond between Hδ− and Hδ+; all observed in one compound, [Li(NH3)4]2B6H6·2NH3.

Graphical abstract: Multi-centre, hydrogen and dihydrogen bonds in lithium closo-hydroborate obtained from liquid ammonia

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Article information

DOI
https://doi.org/10.1039/B804766A
Article type
Communication
Submitted
19 Mar 2008
Accepted
06 May 2008
First published
04 Jun 2008

Dalton Trans., 2008, 3956-3958

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Multi-centre, hydrogen and dihydrogen bonds in lithium closo-hydroborate obtained from liquid ammonia

M. Panda, K. Hofmann, M. H. Prosenc and B. Albert, Dalton Trans., 2008, 3956 DOI: 10.1039/B804766A

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