Issue 33, 2008
From the journal:

Dalton Transactions

Can the hexamethylhydrazinium dication [Me3N–NMe3]2+ be prepared?†‡

Yun Zhanga  and  Christopher A. Reed*a  

* Corresponding authors

a Center for S and P Block Chemistry, Department of Chemistry, University of California, Riverside, California, USA
E-mail: chris.reed@ucr.edu
Fax: +1(951)827 2027

Abstract

The long sought hexamethylhydrazinium(2+) dication, Me3N–NMe32+, calculationally unstable towards “coulombic explosion” because of formal positive charges on adjacent N atoms, can be synthesized and isolated as a CHB11Cl11−carborane salt.

Graphical abstract: Can the hexamethylhydrazinium dication [Me3N–NMe3]2+ be prepared?

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Article information

DOI
https://doi.org/10.1039/B803304H
Article type
Communication
Submitted
26 Feb 2008
Accepted
07 Mar 2008
First published
01 Jul 2008

Dalton Trans., 2008, 4392-4394

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Can the hexamethylhydrazinium dication [Me3N–NMe3]2+ be prepared?

Y. Zhang and C. A. Reed, Dalton Trans., 2008, 4392 DOI: 10.1039/B803304H

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