3D coordination metal–organic frameworks of octacyanometalate bridging between Cu4 magnetic units

Zhao-Xi Wang; Xi-Li Li; Bao-Lin Liu; Hiroko Tokoro; Peng Zhang; You Song; Shin-ichi Ohkoshi; Kazuhito Hashimoto; Xiao-Zeng You

doi:10.1039/B803273B

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3D coordination metal–organic frameworks of octacyanometalate bridging between Cu₄ magnetic units†

Zhao-Xi Wang,^a Xi-Li Li,^a Bao-Lin Liu,^a Hiroko Tokoro,^b Peng Zhang,^a You Song,*^a Shin-ichi Ohkoshi,*^b Kazuhito Hashimoto^b and Xiao-Zeng You^a

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering Nanjing University, Nanjing, China
E-mail: yousong@nju.edu.cn
Fax: +86 (0)25 8331 4502

^b Department of Chemistry, School of Science The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: ohkoshi@light.t.u-tokyo.ac.jp
Fax: +81 (0)3 3812 1896

Abstract

Magnetic Cu₄ clusters with S = 2 are bridged by octacyanometaltate(IV) to form two 3D cluster arrays of metal–organic frameworks. Magnetic investigation shows the ferromagnetic coupling between Cu(II) ions and very weak antiferromagnetic interaction between clusters.

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Article information

DOI: https://doi.org/10.1039/B803273B
Article type: Communication
Submitted: 25 Feb 2008
Accepted: 25 Feb 2008
First published: 13 Mar 2008

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Dalton Trans., 2008, 2103-2106

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3D coordination metal–organic frameworks of octacyanometalate bridging between Cu₄ magnetic units

Z. Wang, X. Li, B. Liu, H. Tokoro, P. Zhang, Y. Song, S. Ohkoshi, K. Hashimoto and X. You, Dalton Trans., 2008, 2103 DOI: 10.1039/B803273B

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Dalton Transactions