Pyridine-based SNS-iridium and -rhodium sulfide complexes, including d8–d8 metal–metal interactions in the solid state†
Abstract
The cationic, pincer-type complexes [(SNS)Ir(COE)][BF4] (1) and [(SNS)Rh(COE)][BF4] (2) (SNS =
* Corresponding authors
a
Department of Organic Chemistry, The Weizmann Institute of Science, Rehovot, Israel
E-mail:
david.milstein@weizmann.ac.il
Fax: 972-8-9344142
b Unit of Chemical Research Support, The Weizmann Institute of Science, Rehovot, Israel
The cationic, pincer-type complexes [(SNS)Ir(COE)][BF4] (1) and [(SNS)Rh(COE)][BF4] (2) (SNS =
Y. Klerman, E. Ben-Ari, Y. Diskin-Posner, G. Leitus, L. J. W. Shimon, Y. Ben-David and D. Milstein, Dalton Trans., 2008, 3226 DOI: 10.1039/B802223B
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