Issue 15, 2008
From the journal:

Dalton Transactions

Palladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene†

Jamie J. R. Frew,a   Matthew L. Clarke,*a   Ulrich Mayer,b   Hendrik Van Rensburgc  and  Robert P. Toozec  

* Corresponding authors

a School of Chemistry, University of St Andrews, St. Andrews, Fife, UK
E-mail: mc28@st-andrews.ac.uk
Fax: +44 1334 463808
Tel: +44 1334 463850

b School of Chemistry, University of Bristol, Bristol, UK

c SASOL Technology UK Ltd., Purdie Building, North Haugh, St. Andrews, Fife, UK

Abstract

Some new bulky fluorinated diphosphines have been prepared and converted to palladium dichloride complexes that have been found to give increased regioselectivity and activity over other Pd–diphosphine systems when used as catalysts for hydroxycarbonylation of styrene.

Graphical abstract: Palladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene

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Article information

DOI
https://doi.org/10.1039/B719012C
Article type
Communication
Submitted
10 Dec 2007
Accepted
28 Jan 2008
First published
18 Feb 2008

Dalton Trans., 2008, 1976-1978

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Palladium complexes of new bulky fluorinated diphosphines give particularly active and regioselective catalysts for hydroxycarbonylation of styrene

J. J. R. Frew, M. L. Clarke, U. Mayer, H. Van Rensburg and R. P. Tooze, Dalton Trans., 2008, 1976 DOI: 10.1039/B719012C

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