A new polyoxometalate-based 3d–4f heterometallic aggregate: a model for the design and synthesis of new heterometallic clusters†‡
Abstract
A new polytungstoarsenate-based 3d–4f heterometallic aggregate has been synthesized, consisting of three {α-AsW10O38} fragments bridged by three {Fe–(µ3-O)3–Ce} heterometallic clusters.