Issue 8, 2008
From the journal:

Dalton Transactions

Halogen-containing tetrametallic aluminium alkoxides†‡

Amitabha Mitra,a   Yuzhong Wang,a   Sean Parkina  and  David Atwood*a  

* Corresponding authors

a Department of Chemistry, University of Kentucky, Lexington, KY, USA
E-mail: Datwood@uky.edu

Abstract

New halogen-containing tetrametallic aluminium alkoxides of formula [Al{(µ-OEt)2AlMeCl}3] (2-cis; 2-trans), and [Al{(µ-OEt)2AlBr2}3] (4), have been synthesized by combining Al(OEt)3 and Me2AlCl (for 2) or EtAlBr2 (for 4). They were fully characterized by (1H, 27Al) NMR, IR, mp, elemental analysis, and single-crystal X-ray diffractometry. The chloride analogue of 4, [Al{(µ-OEt)2AlCl2}3] (3), prepared previously using a different route, was also prepared here by combining Al(OEt)3 and EtAlCl2.

Graphical abstract: Halogen-containing tetrametallic aluminium alkoxides

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B716812H
Article type
Paper
Submitted
31 Oct 2007
Accepted
06 Dec 2007
First published
07 Jan 2008

Dalton Trans., 2008, 1037-1042

Permissions

Request permissions

Halogen-containing tetrametallic aluminium alkoxides

A. Mitra, Y. Wang, S. Parkin and D. Atwood, Dalton Trans., 2008, 1037 DOI: 10.1039/B716812H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements