Issue 1, 2008
From the journal:

Dalton Transactions

Group 13 organoderivatives supported on a metallic oxide model†‡

Octavio González-del Moral,a   Alberto Hernán-Gómez,a   Avelino Martín,a   Miguel Menaa  and  Cristina Santamaría*a  

* Corresponding authors

a Departamento de Química Inorgánica, Universidad de Alcalá, Alcalá de Henares-Madrid, Spain
E-mail: cristina.santamaria@uah.es
Fax: +34 91 8854683
Tel: +34 91 8854629

Abstract

The [{TiCp*(μ-O)}3(μ3–CH)] (1) metalloligand, (Cp* = η5-C5Me5), coordinates in a 1 : 1 ratio to [AlMe3] or 9-BBN to give [{Me3Al}{(μ3-O)(μ-O)2(TiCp*)3(μ3-CH)}] (2) or [{(C8H14)B}(μ-H){(μ3-O)(μ-O)2(TiCp*)3(μ3-CH)}] (4), respectively, partial hydrolysis of 2 leads to the new hydroxo-aluminium derivative [{MeAl}{(μ-OH)(μ3-O)}2{(μ-O)2(TiCp*)3(μ3-CH)}2] (3).

Graphical abstract: Group 13 organoderivatives supported on a metallic oxide model

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Article information

DOI
https://doi.org/10.1039/B716166M
Article type
Communication
Submitted
18 Oct 2007
Accepted
22 Oct 2007
First published
06 Nov 2007

Dalton Trans., 2008, 44-46

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Group 13 organoderivatives supported on a metallic oxide model

O. González-del Moral, A. Hernán-Gómez, A. Martín, M. Mena and C. Santamaría, Dalton Trans., 2008, 44 DOI: 10.1039/B716166M

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