Jump to main content
Jump to site search

Issue 2, 2008
Previous Article Next Article

Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {VVO4} moieties

Author affiliations

Abstract

A family of polyoxometalates with the composition [H2V3M17O62]6– features a Dawson-like architecture containing two tetrahedral {VVO4} templates rather than main group hetero-anions ({PO4} or {SO4} etc.) typically associated with classical heteropolyacids, situated within a mixed-metal {MVI17VIVO54} cage and these clusters were first discovered using mass spectrometry.

Graphical abstract: Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {VVO4} moieties

Back to tab navigation

Supplementary files

Article information


Submitted
17 Sep 2007
Accepted
03 Oct 2007
First published
02 Nov 2007

Dalton Trans., 2008, 214-221
Article type
Paper

Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {VVO4} moieties

H. N. Miras, D. Long, P. Kögerler and L. Cronin, Dalton Trans., 2008, 214
DOI: 10.1039/B714285D

Social activity

Search articles by author

Spotlight

Advertisements