Issue 38, 2008
From the journal:

Physical Chemistry Chemical Physics

Determination of the rate of a fast exchanging coordinated molecule in a lanthanide(iii) complex by proton NMR†

Pascal H. Fries,*a   Marion Girauda  and  Elie Belorizkyb  

* Corresponding authors

a Laboratoire de Reconnaissance Ionique et de Chimie de Coordination, INAC/SCIB (UMR_E 3 CEA-UJF), CEA-Grenoble, Grenoble Cedex 9, France
E-mail: pascal-h.fries@cea.fr

b Laboratoire de Spectrométrie Physique, CNRS-UMR 5588, Université Joseph Fourier, Grenoble 1, BP 87, Saint-Martin d’Hères Cedex, France

Abstract

An elementary procedure is proposed and applied to study the exchange rate of a solvent or solute molecule bound to a complexed paramagnetic Ln(III) ion, other than Gd(III), from the measured longitudinal and transverse relaxation rates and paramagnetic resonance frequency shift at a given temperature.

Graphical abstract: Determination of the rate of a fast exchanging coordinated molecule in a lanthanide(iii) complex by proton NMR

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B806752J
Article type
Communication
Submitted
21 Apr 2008
Accepted
18 Jul 2008
First published
05 Aug 2008

Phys. Chem. Chem. Phys., 2008,10, 5817-5821

Permissions

Request permissions

Determination of the rate of a fast exchanging coordinated molecule in a lanthanide(III) complex by proton NMR

P. H. Fries, M. Giraud and E. Belorizky, Phys. Chem. Chem. Phys., 2008, 10, 5817 DOI: 10.1039/B806752J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements