Issue 42, 2008
From the journal:

Chemical Communications

Rotational spectrum and equilibrium structure of silanethione, H2Si[double bond, length as m-dash]S

Sven Thorwirth,*a   Jürgen Gauss,b   Michael C. McCarthy,c   François Shindoc  and  Patrick Thaddeusc  

* Corresponding authors

a Max-Planck-Institut für Radioastronomie, Auf dem Hügel 69, Germany
E-mail: sthorwirth@mpifr-bonn.mpg.de
Fax: 49 228 525229
Tel: 49 228 525382

b Institut für Physikalische Chemie, Universität Mainz, Germany
E-mail: gauss@uni-mainz.de
Fax: 49 6131 23895
Tel: 49 6131 23736

c School of Engineering and Applied Sciences, Harvard University, 29 Oxford Street, and Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, USA
E-mail: mccarthy@cfa.harvard.edu
Fax: 1 617 4957013
Tel: 1 617 4957262

Abstract

Unsubstituted silanethione, H2Si[double bond, length as m-dash]S, has been characterized experimentally for the first time by means of rotational spectroscopy; the equilibrium structure of this fundamental molecule has been evaluated through a combination of experimental data from a total of ten isotopologues and results of high-level coupled-cluster calculations.

Graphical abstract: Rotational spectrum and equilibrium structure of silanethione, H2Si [[double bond, length as m-dash]] S

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Article information

DOI
https://doi.org/10.1039/B814558J
Article type
Communication
Submitted
20 Aug 2008
Accepted
23 Sep 2008
First published
01 Oct 2008

Chem. Commun., 2008, 5292-5294

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Rotational spectrum and equilibrium structure of silanethione, H2Si[double bond, length as m-dash]S

S. Thorwirth, J. Gauss, M. C. McCarthy, F. Shindo and P. Thaddeus, Chem. Commun., 2008, 5292 DOI: 10.1039/B814558J

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