Enhancing SMM properties via axial distortion of MnIII3clusters

Ross Inglis; Leigh F. Jones; Georgios Karotsis; Anna Collins; Simon Parsons; Spyros P. Perlepes; Wolfgang Wernsdorfer; Euan K. Brechin

doi:10.1039/B811796A

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Enhancing SMM properties via axial distortion of Mn^III₃clusters†

Ross Inglis,^a Leigh F. Jones,^a Georgios Karotsis,^a Anna Collins,^a Simon Parsons,^a Spyros P. Perlepes,^b Wolfgang Wernsdorfer*^c and Euan K. Brechin*^a

Author affiliations

* Corresponding authors

^a School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Tel: +44 0131-650-7545

^b Department of Chemistry, University of Patras, 26504 Patras, Greece

^c Institut Néel, CNRS & Université J. Fourier, BP 166, 38042 Grenoble, France
E-mail: wolfgang.wernsdorfer@grenoble.cnrs.fr

Abstract

Replacement of carboxylate and solvent with facially capping tripodal ligands enhances the single-molecule magnet (SMM) properties of [Mn^III₃] triangles.

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Article information

DOI: https://doi.org/10.1039/B811796A
Article type: Communication
Submitted: 10 Jul 2008
Accepted: 01 Sep 2008
First published: 08 Oct 2008

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Chem. Commun., 2008, 5924-5926

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Enhancing SMM properties via axial distortion of Mn^III₃clusters

R. Inglis, L. F. Jones, G. Karotsis, A. Collins, S. Parsons, S. P. Perlepes, W. Wernsdorfer and E. K. Brechin, Chem. Commun., 2008, 5924 DOI: 10.1039/B811796A

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