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Issue 46, 2008
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Surgery of fullerenes

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Recent attempts at the synthesis of endohedral fullerenes by organic reactions, so-called “molecular surgery” methods, are surveyed. The creation of an opening on the surface of fullerene cages allowed insertion of He, H2, H2O, or CO within the cages. An effective route to “suture” an opening was established to realize a new endohedral fullerene, H2@C60. Further development of this operation as well as the properties and reactions of H2@C60 are summarized. Also the application of the encapsulated H2 molecule as an NMR probe for the study of aromaticity of ionic fullerenes is described.

Graphical abstract: Surgery of fullerenes

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The article was received on 09 Jul 2008, accepted on 22 Aug 2008 and first published on 11 Sep 2008

Article type: Feature Article
DOI: 10.1039/B811738A
Chem. Commun., 2008, 6083-6094

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    Surgery of fullerenes

    M. Murata, Y. Murata and K. Komatsu, Chem. Commun., 2008, 6083
    DOI: 10.1039/B811738A

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