Issue 37, 2008
From the journal:

Chemical Communications

Hydroxylamine as an oxygen nucleophile. Chemical evidence from its reaction with a phosphate triester†

Anthony J. Kirby,*a   Bruno S. Souza,b   Michelle Medeiros,b   Jacks P. Priebe,b   Alex M. Manfredib  and  Faruk Nome*b  

* Corresponding authors

a University Chemical Laboratory, Cambridge, UK
E-mail: ajk1@cam.ac.uk

b Departamento de Química, Universidade Federal de Santa Catarina, Florianópolis, Brazil
E-mail: faruk@qmc.ufsc.br

Abstract

The reaction of hydroxylamine with 2,4-dinitrophenyl diethyl phosphate gives the O-phosphorylated product, which is rapidly converted to hydrazine and nitrogen gas in the presence of the excess of hydroxylamine.

Graphical abstract: Hydroxylamine as an oxygen nucleophile. Chemical evidence from its reaction with a phosphate triester

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Article information

DOI
https://doi.org/10.1039/B810408E
Article type
Communication
Submitted
19 Jun 2008
Accepted
10 Jul 2008
First published
13 Aug 2008

Chem. Commun., 2008, 4428-4429

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Hydroxylamine as an oxygen nucleophile. Chemical evidence from its reaction with a phosphate triester

A. J. Kirby, B. S. Souza, M. Medeiros, J. P. Priebe, A. M. Manfredi and F. Nome, Chem. Commun., 2008, 4428 DOI: 10.1039/B810408E

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