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Issue 42, 2008
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Deprotonative cadmation of functionalized aromatics

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Abstract

This communication describes the deproto-metalation of a large range of aromatics including heterocycles using a newly developed lithium–cadmium base; the reaction proceeds at room temperature with an excellent chemoselectivity and efficiency, and proved to be regioselective in most cases.

Graphical abstract: Deprotonative cadmation of functionalized aromatics

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Publication details

The article was received on 05 Jun 2008, accepted on 16 Jul 2008 and first published on 17 Sep 2008


Article type: Communication
DOI: 10.1039/B809543D
Chem. Commun., 2008, 5375-5377

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    Deprotonative cadmation of functionalized aromatics

    J. L’Helgoual’ch, G. Bentabed-Ababsa, F. Chevallier, M. Yonehara, M. Uchiyama, A. Derdour and F. Mongin, Chem. Commun., 2008, 5375
    DOI: 10.1039/B809543D

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