Manganese catalysed asymmetric cis-dihydroxylation with H2O2

Johannes W. de Boer; Wesley R. Browne; Syuzanna R. Harutyunyan; Laura Bini; Theodora D. Tiemersma-Wegman; Paul L. Alsters; Ronald Hage; Ben L. Feringa

doi:10.1039/B808355J

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Manganese catalysed asymmetric cis-dihydroxylation with H₂O₂†

Johannes W. de Boer,^ab Wesley R. Browne,^a Syuzanna R. Harutyunyan,^a Laura Bini,^c Theodora D. Tiemersma-Wegman,^a Paul L. Alsters,^c Ronald Hage^bd and Ben L. Feringa*^a

Author affiliations

* Corresponding authors

^a Stratingh Institute for Chemistry, Faculty of Mathemathics and Natural Sciences, University of Groningen, Nijenborgh 4, Groningen 9747 AG, The Netherlands
E-mail: b.l.feringa@rug.nl
Fax: +31 50 363 4279

^b Rahu Catalytics, Oliver van Noortlaan 120, 3133 AT Vlaardingen, The Netherlands

^c DSM Pharma Products Innovative Synthesis and Catalysis, PO Box 6160, MD Geelen, The Netherlands

^d Unilever R&D Vlaardingen, PO Box 114, 3130 AC Vlaardingen, The Netherlands

Abstract

High turnover enantioselectivealkenecis-dihydroxylation is achieved with H₂O₂ catalysed by manganese based complexes containing chiral carboxylato ligands.

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Supplementary files

Synthesis and characterisation of all complexes andcompounds, experimental procedures, NMR analysis, discussion ofanalysis methods PDF (2243K)

Article information

DOI: https://doi.org/10.1039/B808355J
Article type: Communication
Submitted: 19 May 2008
Accepted: 25 Jun 2008
First published: 17 Jul 2008

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Chem. Commun., 2008, 3747-3749

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Manganese catalysed asymmetric cis-dihydroxylation with H₂O₂

J. W. de Boer, W. R. Browne, S. R. Harutyunyan, L. Bini, T. D. Tiemersma-Wegman, P. L. Alsters, R. Hage and B. L. Feringa, Chem. Commun., 2008, 3747 DOI: 10.1039/B808355J

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