Issue 39, 2008
From the journal:

Chemical Communications

Self-assembling squares with amino acid-decorated bipyridines: heterochiral self-sorting of dynamically interconverting diastereomers†‡

Alexander Rang,ab   Martin Nieger,c   Marianne Engeser,b   Arne Lützenb  and  Christoph A. Schalley*a  

* Corresponding authors

a Institut für Chemie und Biochemie der Freien Universität, Takustr. 3, Berlin, Germany
E-mail: schalley@chemie.fu-berlin.de

b Kekulé-Institut für Organische Chemie und Biochemie der Universität, Gerhard-Domagk-Str. 1, Bonn, Germany

c Laboratory of Inorganic Chemistry, FIN-00014 University of Helsinki, Finland

Abstract

Heterochiral self-sorting into only one stereoisomer is observed when metallo-supramolecular squares self-assemble from amino acid-substituted, dynamically interconverting bipyridine stereoisomers and dpppM(OTf)2 corners (M = Pd, Pt).

Graphical abstract: Self-assembling squares with amino acid-decorated bipyridines: heterochiral self-sorting of dynamically interconverting diastereomers

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Article information

DOI
https://doi.org/10.1039/B806916F
Article type
Communication
Submitted
23 Apr 2008
Accepted
27 Jun 2008
First published
12 Aug 2008

Chem. Commun., 2008, 4789-4791

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Self-assembling squares with amino acid-decorated bipyridines: heterochiral self-sorting of dynamically interconverting diastereomers

A. Rang, M. Nieger, M. Engeser, A. Lützen and C. A. Schalley, Chem. Commun., 2008, 4789 DOI: 10.1039/B806916F

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