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Issue 35, 2008

Methylidynearsine (HC[triple bond, length as m-dash]As): synthesis and direct characterization by UV-photoelectron spectroscopy and mass spectrometry

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Abstract

The dehydrohalogenation of gaseous dichloromethylarsine on solid base led to chloromethylidenearsine and, at higher temperature of the base, to methylidynearsine, the third unsubstituted heteroalkyne unambiguously synthesized up to now.

Graphical abstract: Methylidynearsine (HC [[triple bond, length as m-dash]] As): synthesis and direct characterization by UV-photoelectron spectroscopy and mass spectrometry

Supplementary files

Article information


Submitted
22 Apr 2008
Accepted
27 May 2008
First published
10 Jul 2008

Chem. Commun., 2008, 4204-4206
Article type
Communication

Methylidynearsine (HC[triple bond, length as m-dash]As): synthesis and direct characterization by UV-photoelectron spectroscopy and mass spectrometry

J. Guillemin, A. Chrostowska, A. Dargelos, T. X. M. Nguyen, A. Graciaa and P. Guenot, Chem. Commun., 2008, 4204 DOI: 10.1039/B806771F

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