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Abstract | Cited by

An investigation of the photophysics of Ir(III) complexes with controlled ligand structures and our quantum chemical calculations attest that the most probable explanation for the reported ‘aggregation-induced phosphorescent emission’, which was originally claimed to be related to an intermolecular excimer, is restricted intramolecular motion.

Graphical abstract: Comment on ‘aggregation-induced phosphorescent emission (AIPE) of iridium(iii) complexes’: origin of the enhanced phosphorescence

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