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Issue 43, 2008
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Covalent surface modification of a metal–organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition

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Abstract

A Zn-cornered, mixed-ligand, metal–organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via‘click chemistry’, in a demonstration of selective post-synthesis functionalization.

Graphical abstract: Covalent surface modification of a metal–organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition

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Publication details

The article was received on 26 Mar 2008, accepted on 15 Aug 2008 and first published on 08 Oct 2008


Article type: Communication
DOI: 10.1039/B805101A
Chem. Commun., 2008, 5493-5495

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    Covalent surface modification of a metal–organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition

    T. Gadzikwa, G. Lu, C. L. Stern, S. R. Wilson, J. T. Hupp and S. T. Nguyen, Chem. Commun., 2008, 5493
    DOI: 10.1039/B805101A

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