Jump to main content
Jump to site search

Issue 24, 2008
Previous Article Next Article

Hydrogen bonding directs the H2O2oxidation of platinum(ii) to a cis-dihydroxo platinum(iv) complex

Author affiliations

Abstract

The use of ligands with proximate hydrogen bonding substituents in the oxidation of platinum(II) dimethyl complexes with H2O2 leads to the exclusive formation of an unusual cis-dihydroxo platinum(IV) complex, which can dehydrate to form a trinuclear metalla-azacrown complex.

Graphical abstract: Hydrogen bonding directs the H2O2 oxidation of platinum(ii) to a cis-dihydroxo platinum(iv) complex

Back to tab navigation

Supplementary files

Article information


Submitted
28 Feb 2008
Accepted
19 Mar 2008
First published
11 Apr 2008

Chem. Commun., 2008, 2800-2802
Article type
Communication

Hydrogen bonding directs the H2O2 oxidation of platinum(II) to a cis-dihydroxo platinum(IV) complex

R. A. Taylor, D. J. Law, G. J. Sunley, A. J. P. White and G. J. P. Britovsek, Chem. Commun., 2008, 2800
DOI: 10.1039/B803370F

Social activity

Search articles by author

Spotlight

Advertisements