Issue 25, 2008
From the journal:

Chemical Communications

Hysteretic sorption of light gases by a porous metal–organic framework containing tris(para-carboxylated) triphenylphosphine oxide†‡

Simon M. Humphrey,*ab   Shaunt E. Oungoulian,a   Ji Woong Yoon,c   Young Kyu Hwang,c   Erica R. Wisea  and  Jong-San Chang*c  

* Corresponding authors

a University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: smh49@cam.ac.uk
Fax: +44 (0)1223 336017
Tel: +44 (0)1223 336396

b St. John’s College, Cambridge, UK

c Catalysis Centre for Molecular Engineering, Korea Research Institute of Chemical Technology, PO Box 107, Yusung, Daejeon, Korea
E-mail: jschang@krict.re.kr

Abstract

The porous metal–organic framework (MOF) PCM-4, based on tris(para-carboxylated) triphenylphosphine oxide, contains atypical, polar organic substituents; the material exhibits a hysteretic sorption of Ar, N2 and O2, and demonstrates the advantage of ligands of this type.

Graphical abstract: Hysteretic sorption of light gases by a porous metal–organic framework containing tris(para-carboxylated) triphenylphosphine oxide

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Article information

DOI
https://doi.org/10.1039/B802809E
Article type
Communication
Submitted
19 Feb 2008
Accepted
31 Mar 2008
First published
21 Apr 2008

Chem. Commun., 2008, 2891-2893

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Hysteretic sorption of light gases by a porous metal–organic framework containing tris(para-carboxylated) triphenylphosphine oxide

S. M. Humphrey, S. E. Oungoulian, J. W. Yoon, Y. K. Hwang, E. R. Wise and J. Chang, Chem. Commun., 2008, 2891 DOI: 10.1039/B802809E

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