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Issue 24, 2008
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A rare ligand bridged ferromagnetically coupled MnIV3 complex with a ground spin state of S = 9/2

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Abstract

An exclusively chelating ligand bridged high-valent [MnIV3] complex has been synthesized, in which all MnIV ions are ferromagnetically-coupled to exhibit an ST = 9/2 spin ground state.

Graphical abstract: A rare ligand bridged ferromagnetically coupled MnIV3 complex with a ground spin state of S = 9/2

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Publication details

The article was received on 11 Feb 2008, accepted on 26 Mar 2008 and first published on 16 Apr 2008


Article type: Communication
DOI: 10.1039/B802279H
Chem. Commun., 2008, 2782-2784

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    A rare ligand bridged ferromagnetically coupled MnIV3 complex with a ground spin state of S = 9/2

    T. Pathmalingam, S. I. Gorelsky, T. J. Burchell, A. Bédard, A. M. Beauchemin, R. Clérac and M. Murugesu, Chem. Commun., 2008, 2782
    DOI: 10.1039/B802279H

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