Issue 12, 2008
From the journal:

Chemical Communications

Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes†

Toshimichi Ohmura,a   Kazuyuki Oshimaa  and  Michinori Suginome*a  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: suginome@sbchem.kyoto-u.ac.jp
Fax: +81-75-383-2722

Abstract

Palladium-catalysed cis- and trans-silaboration of terminal alkynes has been developed via the addition of (chlorodimethylsilyl)pinacolborane, followed by a one-pot conversion of the chloro group on the silicon atom to an isopropoxy group.

Graphical abstract: Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes

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Article information

DOI
https://doi.org/10.1039/B800181B
Article type
Communication
Submitted
08 Jan 2008
Accepted
01 Feb 2008
First published
18 Feb 2008

Chem. Commun., 2008, 1416-1418

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Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes

T. Ohmura, K. Oshima and M. Suginome, Chem. Commun., 2008, 1416 DOI: 10.1039/B800181B

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