Issue 12, 2008

Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes

Abstract

Palladium-catalysed cis- and trans-silaboration of terminal alkynes has been developed via the addition of (chlorodimethylsilyl)pinacolborane, followed by a one-pot conversion of the chloro group on the silicon atom to an isopropoxy group.

Graphical abstract: Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes

Supplementary files

Article information

Article type
Communication
Submitted
08 Jan 2008
Accepted
01 Feb 2008
First published
18 Feb 2008

Chem. Commun., 2008, 1416-1418

Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes

T. Ohmura, K. Oshima and M. Suginome, Chem. Commun., 2008, 1416 DOI: 10.1039/B800181B

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