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Issue 13, 2008
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Regioselective 12CO/13CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the Hox state of [FeFe]-hydrogenase

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Abstract

A mixed-valent Fe(II)Fe(I) model of the Hox state of [FeFe]-hydrogenase is shown, under certain conditions, to exhibit regioselective 12CO/13CO exchange activity similar to that observed for Hox.

Graphical abstract: Regioselective 12CO/13CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the Hox state of [FeFe]-hydrogenase

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Supplementary files

Article information


Submitted
20 Dec 2007
Accepted
23 Jan 2008
First published
20 Feb 2008

Chem. Commun., 2008, 1563-1565
Article type
Communication

Regioselective 12CO/13CO exchange activity of a mixed-valent Fe(II)Fe(I) model of the Hox state of [FeFe]-hydrogenase

C. M. Thomas, T. Liu, M. B. Hall and M. Y. Darensbourg, Chem. Commun., 2008, 1563
DOI: 10.1039/B719559A

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