Synthesis and styrene polymerisation catalysis of η5- and η1-pyrrolyl-ligated cationic rare earth metal aminobenzyl complexes

Masayoshi Nishiura; Tomohiro Mashiko; Zhaomin Hou

doi:10.1039/B719182K

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Synthesis and styrenepolymerisation catalysis of η⁵- and η¹-pyrrolyl-ligated cationic rare earth metal aminobenzyl complexes†

Masayoshi Nishiura,^a Tomohiro Mashiko^a and Zhaomin Hou*^a

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* Corresponding authors

^a Organometallic Chemistry Laboratory, RIKEN (The Institute of Physical and Chemical Research), Hirosawa 2-1, Wako, Saitama 351-0198, Japan
E-mail: houz@riken.jp
Fax: +81 48 462 4665
Tel: +81 48 467 9393

Abstract

The cationic rare earth metal aminobenzyl complexes bearing mono(pyrrolyl) ligands are synthesised and structurally characterised, and the coordination mode of the pyrrolyl ligands is found to show significant influence on the polymerisation of styrene.

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Article information

DOI: https://doi.org/10.1039/B719182K
Article type: Communication
Submitted: 13 Dec 2007
Accepted: 04 Feb 2008
First published: 25 Feb 2008

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Chem. Commun., 2008, 2019-2021

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Synthesis and styrene polymerisation catalysis of η⁵- and η¹-pyrrolyl-ligated cationic rare earth metal aminobenzyl complexes

M. Nishiura, T. Mashiko and Z. Hou, Chem. Commun., 2008, 2019 DOI: 10.1039/B719182K

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