Issue 17, 2008

Synthesis and styrenepolymerisation catalysis of η5- and η1-pyrrolyl-ligated cationic rare earth metal aminobenzyl complexes

Abstract

The cationic rare earth metal aminobenzyl complexes bearing mono(pyrrolyl) ligands are synthesised and structurally characterised, and the coordination mode of the pyrrolyl ligands is found to show significant influence on the polymerisation of styrene.

Graphical abstract: Synthesis and styrene polymerisation catalysis of η5- and η1-pyrrolyl-ligated cationic rare earth metal aminobenzyl complexes

Supplementary files

Article information

Article type
Communication
Submitted
13 Dec 2007
Accepted
04 Feb 2008
First published
25 Feb 2008

Chem. Commun., 2008, 2019-2021

Synthesis and styrene polymerisation catalysis of η5- and η1-pyrrolyl-ligated cationic rare earth metal aminobenzyl complexes

M. Nishiura, T. Mashiko and Z. Hou, Chem. Commun., 2008, 2019 DOI: 10.1039/B719182K

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