In situ        recrystallisation of a coordination polymer with hemilabile linkers

Philip I. Richards; Jamie F. Bickley; Ramamoorthy Boomishankar; Alexander Steiner

doi:10.1039/B718872B

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In siturecrystallisation of a coordination polymer with hemilabile linkers

Philip I. Richards,^a Jamie F. Bickley,^a Ramamoorthy Boomishankar^a and Alexander Steiner*^a

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* Corresponding authors

^a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK
E-mail: a.steiner@liv.ac.uk

Abstract

The variable coordination pattern of a hemilabile phosphazene ligand equipped with six pendent olefin groups facilitates the in siturecrystallisation of a silver(I) complex from an amorphous precipitate into a 1D coordination polymer and its subsequent isomerisation to a 3D coordination network.

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Supplementary files

Crystal structure data TXT (67K)

Article information

DOI: https://doi.org/10.1039/B718872B
Article type: Communication
Submitted: 06 Dec 2007
Accepted: 11 Jan 2008
First published: 01 Feb 2008

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Chem. Commun., 2008, 1656-1658

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In situ recrystallisation of a coordination polymer with hemilabile linkers

P. I. Richards, J. F. Bickley, R. Boomishankar and A. Steiner, Chem. Commun., 2008, 1656 DOI: 10.1039/B718872B

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