A very high catalytic activity in the cyanosilylation reaction was observed for MIL-101, a chromium based metal–organic framework; moreover, MIL-101 is also a remarkably stable support for palladium in hydrogenation reactions, with significantly higher activity than e.g.palladium on activated carbon.
A. Henschel, K. Gedrich, R. Kraehnert and S. Kaskel, Chem. Commun., 2008, 4192 DOI: 10.1039/B718371B
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