Issue 10, 2008
From the journal:

Chemical Communications

Rapid and efficient entry to vinyl silanes from aldehydes employing a novel metalation–Peterson sequence†

James McNulty*a  and  Priyabrata Dasa  

* Corresponding authors

a Department of Chemistry, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada
E-mail: jmcnult@mcmaster.ca
Fax: +1 905-522-2509
Tel: +1 905-525-9140 ext. 27393

Abstract

Bis(trimethylsilyl)chloromethane undergoes a rapid and selective metalation with s-BuLi, yielding the nucleophilicbis(trimethylsilyl)methyl anion and providing a straightforward general entry to vinyl silanes from aromatic, aliphatic and vinyl aldehydes.

Graphical abstract: Rapid and efficient entry to vinyl silanes from aldehydes employing a novel metalation–Peterson sequence

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Article information

DOI
https://doi.org/10.1039/B716897G
Article type
Communication
Submitted
05 Nov 2007
Accepted
18 Jan 2008
First published
07 Feb 2008

Chem. Commun., 2008, 1244-1245

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Rapid and efficient entry to vinyl silanes from aldehydes employing a novel metalation–Peterson sequence

J. McNulty and P. Das, Chem. Commun., 2008, 1244 DOI: 10.1039/B716897G

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