Issue 11, 2008
From the journal:

Chemical Communications

Cu-catalyzed regioselective carbomagnesiation of dienes and enynes with sec- and tert-alkyl Grignard reagents†

Hirohisa Todo,a   Jun Terao,*b   Hideyuki Watanabe,a   Hitoshi Kuniyasua  and  Nobuaki Kambe*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Japan
E-mail: kambe@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7390
Tel: +81-6-6879-7388

b Science and Technology Centre for Atoms, Molecules and Ions Control, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Japan
E-mail: terao@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7390
Tel: +81-6-6879-7389

Abstract

The carbomagnesiation of dienes and enynes with sec- and tert-alkyl Grignard reagents has been achieved by using copper salts as catalysts.

Graphical abstract: Cu-catalyzed regioselective carbomagnesiation of dienes and enynes with sec- and tert-alkyl Grignard reagents

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Article information

DOI
https://doi.org/10.1039/B716678H
Article type
Communication
Submitted
30 Oct 2007
Accepted
11 Dec 2007
First published
11 Jan 2008

Chem. Commun., 2008, 1332-1334

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Cu-catalyzed regioselective carbomagnesiation of dienes and enynes with sec- and tert-alkyl Grignard reagents

H. Todo, J. Terao, H. Watanabe, H. Kuniyasu and N. Kambe, Chem. Commun., 2008, 1332 DOI: 10.1039/B716678H

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