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Issue 4, 2008
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Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N3P3Cl6] catalyzed by silylium ions

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Abstract

The temperature required for ring-opening polymerisation of cyclo-N3P3Cl6 can be dramatically lowered by employing trialkylsilylium carboranes [R3Si(CHB11X11] as catalysts.

Graphical abstract: Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N3P3Cl6] catalyzed by silylium ions

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Article information


Submitted
12 Sep 2007
Accepted
21 Nov 2007
First published
11 Dec 2007

Chem. Commun., 2008, 494-496
Article type
Communication

Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N3P3Cl6] catalyzed by silylium ions

Y. Zhang, K. Huynh, I. Manners and C. A. Reed, Chem. Commun., 2008, 494
DOI: 10.1039/B713933K

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