Diazoalkanes react with a bis(phosphino)borate copper(I) source to generate [Ph2BPtBu2]Cu(η1-N2CR2), [Ph2BPtBu2]Cu(CPh2), and [Ph2BPtBu2]Cu–N(CPh2)(NCPh2)

Neal P. Mankad; Jonas C. Peters

doi:10.1039/B713687K

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Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph₂BP^tBu₂]Cu(η¹-N₂CR₂), [Ph₂BP^tBu₂]Cu(CPh₂), and [Ph₂BP^tBu₂]Cu–N(CPh₂)(NCPh₂)†

Neal P. Mankad^a and Jonas C. Peters*^a

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* Corresponding authors

^a Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA
E-mail: jcpeters@mit.edu

Abstract

[Ph₂BP^tBu₂]Cu–L complexes react with diazoalkanes to generate structurally unusual η¹-diazoalkane adducts, a terminal carbene, and an η¹-azine adduct.

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Article information

DOI: https://doi.org/10.1039/B713687K
Article type: Communication
Submitted: 06 Sep 2007
Accepted: 14 Dec 2007
First published: 17 Jan 2008

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Chem. Commun., 2008, 1061-1063

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Diazoalkanes react with a bis(phosphino)borate copper(I) source to generate [Ph₂BP^tBu₂]Cu(η¹-N₂CR₂), [Ph₂BP^tBu₂]Cu(CPh₂), and [Ph₂BP^tBu₂]Cu–N(CPh₂)(NCPh₂)

N. P. Mankad and J. C. Peters, Chem. Commun., 2008, 1061 DOI: 10.1039/B713687K

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