Issue 4, 2008

Molecular recognition in homogeneous transition metal catalysis: a biomimetic strategy for high selectivity

Abstract

Traditional methods for selectivity control in homogeneous transition metal catalysis either employ steric effects in a binding pocket or chelate control. In a supramolecular strategy, encapsulation of the substrate can provide useful shape and size selectivity. A fully developed molecular recognition strategy involving hydrogen bonding or solvophobic forces has given almost completely regioselective functionalization of remote, unactivated C–H bonds.

Graphical abstract: Molecular recognition in homogeneous transition metal catalysis: a biomimetic strategy for high selectivity

Article information

Article type
Feature Article
Submitted
06 Jul 2007
Accepted
31 Aug 2007
First published
14 Sep 2007

Chem. Commun., 2008, 413-424

Molecular recognition in homogeneous transition metal catalysis: a biomimetic strategy for high selectivity

S. Das, G. W. Brudvig and R. H. Crabtree, Chem. Commun., 2008, 413 DOI: 10.1039/B710355G

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