Issue 3, 2008

Self-healing materials: a review


The ability of materials to self-heal from mechanical and thermally induced damage is explored in this paper and has significance in the field of fracture and fatigue. The history and evolution of several self-repair systems is examined including nano-beam healing elements, passive self-healing, autonomic self-healing and ballistic self-repair. Self-healing mechanisms utilized in the design of these unusual materials draw much information from the related field of polymerpolymer interfaces and crack healing. The relationship of material damage to material healing is examined in a manner to provide an understanding of the kinetics and damage reversal processes necessary to impart self-healing characteristics. In self-healing systems, there are transitions from hard-to-soft matter in ballistic impact and solvent bonding and conversely, soft-to-hard matter transitions in high rate yielding materials and shear-thickening fluids. These transitions are examined in terms of a new theory of the glass transition and yielding, viz., the twinkling fractal theory of the hard-to-soft matter transition. Success in the design of self-healing materials has important consequences for material safety, product performance and enhanced fatigue lifetime.

Graphical abstract: Self-healing materials: a review

Article information

Article type
Review Article
31 Jul 2007
30 Nov 2007
First published
10 Jan 2008

Soft Matter, 2008,4, 400-418

Self-healing materials: a review

R. P. Wool, Soft Matter, 2008, 4, 400 DOI: 10.1039/B711716G

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